Table of Contents
The Atom and the Atomic Structure
Atoms are the basic units of all matter. They consist of a positively charged nucleus and a negatively charged shell in which the electrons move in fixed, elliptical orbits.
Atoms are made of three fundamental particles:
|Electrons||-1||5.4859 x 10-4|
Atoms and elements are defined by three numbers relating to the composition of the nucleus:
- Z – the ATOMIC (or ELEMENT) number
- N – the NEUTRON number
- A – the MASS number
To properly identify an atom it is written as follows:
The atomic core (nucleus) possesses positively charged protons and neutrons, which have no charge. What’s special about the nucleus is that compared to the electron shell it is much smaller, but at the same time accounts for 99 % of the mass of the whole atom.
Nuclide and nucleons
The nuclide is a particular type of nucleus, which is precisely defined by the number of specific nucleons inside it. Nucleons are a collective term used to refer to subatomic particles inside the nucleus which are the protons and the neutrons. Nuclides having the equal number of proton, but a different number of neutrons belong to the same element but are referred to as isotopes.
Isotopes represent atoms of the same element that differ in the number of neutrons. If the mass number in the Periodic System of Elements (PSE) represents a fraction, the naturally occurring isotopes will be taken into account as a percentage. To calculate the mass number, the following equation is used.
Example: carbon, atomic number 6 (which means 6 protons and 6 neutrons), mass number 12.011
- 6 + 6 = 12 → according to the mass number it is a difference of 0.011
- Conclusion: in some atoms of the element carbon there are in a certain ratio different numbers of neutrons, so-called isotopes.
For approximately 20 of the mononuclidic elements (including sodium, phosphorus, and fluorine) exists only one stable isotope, and so they are called anisotopic elements.
The so-called mixing elements are elements that contain different stable isotopes such as hydrogen, which contains the stable isotopes protium and tritium.
In the shell of the atoms, the electrons move in elliptical orbits around the nucleus. The electrons fill the shells from the inside to the outside. These are chronologically numbered, starting with the letter K. This means that the first or the innermost shell is called “K”, the second one “L”, and the third one “M” etc.
Atoms are neutral-charged particles which means that they possess the same number of electrons and protons. If an atom releases an electron as part of a reaction and incorporates other electrons, then it is called a charged atom, or a so-called ion. Positive ions, where fewer electrons than protons are present, are referred to as cations. Negative ions, therefore, ions with an excess of electrons, are known as anions.
Ions of the main elements follow the octet rule to attain noble gas configuration.
The Periodic System of Elements (PSE)
The PSE is developed and structured based on the atomic structure. It reflects the coherence between structure and properties of the elements and other information, such as electronegativity, are indicated.
The elements are arranged in order of the increasing atomic number (= ordinal number) which also represents the number of protons.
They are divided into groups and not randomly strung together. Elements of the same group possess the same number of valence electrons (outer electrons, which may be involved in atomic bonds). The groups are differentiated into primary and secondary groups. The s- and p-orbitals play the only important role in the main group elements, since the d- and f-orbitals are less used for bond formation as they have more complicated reaction chemistry.
The simplest orbital is the s-orbital (I=0) which is a sphere:
p-Orbitals (I=1) are more complex than s and come in three different types:
A p-orbital has two regions where the electrons may be found either side of the nucleus:
- Nodal plane
- no electron density
- containing the nucleus
- are either labeled + or – or given different colors
- they are said to have different phases
This originates from the wavefunction which defines the orbital:
In contrast, the d- and f-orbitals play an important role in the subgroup elements since their partial occupation decisively influences the properties of transition elements (see electron configuration).
Furthermore, the PSE can be horizontally divided into periods. The number of the period corresponds to the number of the occupied shells after the Bohr atom model.
Metals can be found on the left bottom of the PSE, non-metals on the right top.
Mendeleev developed in 1869 the law of periodicity based on the regular repetition of similar element characteristics. The periodicity described by him is based on the internal structure of atoms and their shell in particular.
The periods and the main groups reflect the legitimacy:
- Atomic radius (= half the distance between the nuclei of adjacent, identical atoms): within a period the atomic radii of the main group elements decreases as the atomic number increases because electrons are pulled closer towards the nucleus because of the higher number of positively charged protons in the nucleus. Within a group (from the light to the heavy elements), the atomic radii increase as the number of occupied energy levels (shells) increases.
- Mass: the mass increases within the main groups from top to bottom and within the periods from left to right, which correlates with the increasing number of subatomic particles inside an atom.
- Electronegativity: (a measure of the tendency of an atom to tighten the bonding electron pair in an atomic compound): the electronegativity of elements increases within a period as the number of protons and the effective nuclear charge rises.
This means that in a connection between different atoms the electronegative partner pulls reinforced the electron pair in its direction so that the electron pair is no longer located symmetrically between the participating atoms. The electronegativity decreases in these groups because the effective nuclear charge decreases by shielding of the inner orbitals.
The subgroup elements represent the transition metals. The essential biochemical subgroup elements, e.g. zinc, iron, manganese and much more, are called trace elements and should be periodically taken in small amounts by the human organism. These are important for the function of metalloenzymes.
Electron configuration and the orbital model
The atoms can be illustrated next to the pictorial visualizations with other illustration facilities, such as the energy level scheme and the electron configuration.
The electron configuration displays the distribution of electrons in the atomic orbitals. It is specific for each atom.
The electron configuration is established by listing each orbital. Therefore, some information is of high relevance. The following factors are to be considered:
Is it a main or subgroup element?
→ In case of a main group element, the last occupied orbital is an s- or p-orbital.
→ In case of a subgroup element, the last occupied orbital is a d- or f-orbital.
In which period is the atom?
→ The highest level corresponds to the period in which the atom is located.
→ Total of the exponents reveals the atomic number.
In order to deliver the correct electron configuration, there are some rules to follow:
- Aufbau principle: The structure is based on the energetic order, beginning with the lowest energy orbital (s-orbital).
- Pauli principle: An orbital contains a maximum of 2 electrons.
- Hund’s rule: Orbitals of the same energy are filled individually.
How the electron configuration of an atom is stated will tell you also of the oxidation number state of the atom.
The oxidation number represents the amount of electrons that have been accepted or released by an atom compared to its neutral elemental state.
The oxidation number indicates the ionic charge (valence).
The goal of each atom is to reach noble gas configuration and to achieve this, the atoms will either release or accept electrons.
To determine the oxidation number of an atom in a substance, a number of principles and rules must be observed:
- Pure elements have elements equal to zero.
- Metals have high tendency to release electrons and so they are positively charged.
- Fluorine: -1
- Hydrogen: +1
- Oxygen: -2
- Halogens: -1
Example: H2O2 → H: +1; O: -1 (the oxidation number of hydrogens stands in the hierarchy above the oxidation number of oxygen and therefore hydrogens receives its oxidation number as given in the list above)
- Compounds to the outside ±0
- Ions outwardly according to their ionic change
Here you can find everything concerning chemical bonding.
States of Matter and Stage Boundaries
States of matter
A substance can be solid, liquid or gas.
- Solid (s): The molecules of a substance are to be found in a crystal-like structure.
- Liquid (l): The molecules are held together in a liquid bandage by the forces of attraction, but are mutually movable.
- Gaseous (g): The molecules are relatively far apart from each other so that mutual interactions are low.
This means the change of a state of matter.
During a stage boundary, two phases simultaneously coexist, e.g. ice-water-mixture, water-water steam.
Energy is always consumed during a change of state. If energy is supplied during a stage boundary in one direction, the energy will get free in the other direction again.
The following common terms should be known:
solid → liquid: melting
liquid → solid: freezing
liquid → gaseous: vaporizing
gaseous → liquid: condensing
solid → gaseous: sublimating
gaseous → solid: precipitating
Chemical substances react, while constructing or dissolving bonds. If forward and reverse reactions plateau after a certain time, there will be a balance of products and reagents.
Important reaction types in inorganic systems are the redox reaction and the acid-base reaction.
On the other hand, a Bronsted base is characterized by the property to accept protons, which means that they can act as a proton acceptor. If an acid and a base react with each other, this is called acid-base-neutralization reaction. The oxidation numbers do not change, unlike in redox reactions.
- NaOH is a base: in an aqueous solution, it dissociates into Na+ und OH–. The hydroxide ions are taken by hydrogen ions and water accrues.
- Cl is an acid: in an aqueous solution, HCl reacts with to produce the hydronium and chloride ion.
HCl(aq) + H2O(l) H3O+(aq) + Cl–(aq)
- According to this model, an acid evolves a proton, which means that an oxygen molecule accepts H+ and forms a hydronium ion (H3O+) on the side of the products. HCl and Cl– represent in this reaction the conjugated acid-base-pair 1 and H2O and H3O+ the conjugated acid-base-pair 2.
A special form of the acid-base-reaction is the neutralization. The neutralization is a chemical reaction, in which hydrogen ions and hydroxide ions connect with each other to form water.
Word equation: hydroxide + acid → salt + water
The redox reaction is a reaction with electron transition, in which the redox reaction and the reduction take place with each other as a partial reaction. During oxidation, their atoms donate electrons leading to a more positive oxidation state. On the other hand, during reduction, atoms accept electrons leading to a more negative oxidation state.
The precondition for a redox reaction is the presence of two corresponding electron pairs.
As given in the example, CuO is reduced and afterward called an oxidant. Furthermore, it is seen that the oxidation number of copper changes, while the oxidation number of oxygen stays the same. This means that the atom of copper is part of the copper oxide-compound, which accepts electrons and therefore is involved in the electron transfer.
H2 is oxidized, which means that the electrons will be released and it acts as a reductant.
The acid-base-reaction, as well as the redox reaction, are donor-acceptor-reactions. The difference is that in the acid-base-reactions protons are transferred, whereas, in the redox reaction, electrons are transferred.
Quantitative Analysis (Chemical Calculation)
The basic requirement for all chemical calculations is the knowledge of the essential size, dimensions and fundamental units, which are the so-called SI-Units (Système international d’unités).
Unit of the atomic mass: 1 u → compares the mass of a hydrogen atom with another atom
Amount of substance n: 1 mol = 6 × 10-23 → n = m/M
Mass m: 1 kg
Molar mass M: 1 g/mol → M = m/n
Substance concentration c: 1 mol/cm3
Volume V: 1 m³
Law of mass action (LMA)
The LMA provides the mathematical basis for calculating the ratio between products and reactants in an adjusted balance based on the prevailing substance concentration. The ratio K is constant for a specific reaction with the same conditions.
- Only valid for closed systems
- Only valid for selected equilibria
K = equilibrium/ mass action constant
Stoichiometric numbers of reaction numbers must be considered as an exponent in the LMA.
The calorimetry deals with measurements of the released or absorbed heat quantities of chemical reactions.
- High rate of reaction
- Complete sequence of chemical reactions
- Measurable heat turnover
Equitation for calorimetric calculations:
[cp H2O = 4,19 kJ × kg-1 × K-1]
[RP = reaction product]
This theorem states that the molecular reaction enthalpy depends only on the initial and final condition and is independent of the reaction pathway.
If it is not possible to measure the reaction enthalpy directly, it is feasible to determine the reaction enthalpy by the Hess theorem indirectly. For this, the enthalpies of the chemical reactions can be calculated by the listed enthalpy of formation and enthalpy of combustion.
The pH-value is the negative decadic logarithm of the hydronium-concentration (at 25°C) and therefore is a measure of how acid or basic a solution is.
This calculation is particularly relevant for the acid-base-reactions.
Given: 0.2 mol/L HCl solution
Since HCl is a strong acid, the concentration of the acid is equal to the concentration of H+.
pH = – log[H+] = -log [0.2] = 0.7
→ 0.7 < 7 this means that it is a highly acidic solution.
Possible Exam Questions
The answers can be found below the references.
1. How many electrons fit on the outmost shell of the noble gas of the third period (argon)?
2. To which statement about the PSE can you correctly agree?
- Within a period, the atomic radii of main group elements are reducing.
- With increasing atomic number, the mass of an atom decreases.
- Elements of the same period have the same number of valence electrons.
- Alkali metals achieve noble gas configuration by accepting electrons.
- Based on the electronegativity value of an element, the type of binding, which they will enter, can be read out directly.
3. The redox reaction is a reaction with electron transfer. Which of the following statements does not match the character of the redox reaction?
- The oxidation and reduction always proceed parallel.
- The oxidizing agent will be reduced and the reduction agent will be oxidized.
- The oxidation takes place under electron donation, whereas the reduction takes place under electron acceptance.
- Mandatory requirement for the redox reaction is the presence of at least one corresponding pair of electrons.
- The redox reaction numbers among as a chemical reaction to the donor-acceptor-reactions.